Procedure for preparation of Co/Al coordinated conjugated microporous polymer
نویسندگان
چکیده
منابع مشابه
A Conjugated Microporous Polymer for Palladium‐Free, Visible Light‐Promoted Photocatalytic Stille‐Type Coupling Reactions
The Stille coupling reaction is a versatile method to mainly form aromatic C-C bonds. However, up to now, the use of palladium catalysts is necessary. Here, a palladium-free and photocatalytic Stille-type coupling reaction of aryl iodides and aryl stannanes catalyzing a conjugated microporous polymer-based phototcatalyst under visible light irradiation at room temperature is reported. The novel...
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Oils, organic solvents, dyes, and heavy metal ions are primary pollutants in water resources. Currently, no sorbent material can effectively remove these types of pollutants simultaneously. Here we report a perfluorous conjugated microporous polymer with superhydrophobicity and a large surface area, which exhibits outstanding adsorption capacities, kinetics, and recyclability for a wide range o...
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CMP as large surface area materials have attracted growing interest recently, due to their high variability in the incorporation of functional groups in combination with their outstanding thermal and chemical stability, and low densities. However, their insoluble nature causes problems in their processing since usually applied techniques such as spin coating are not available. Especially for me...
متن کاملCapture and conversion of CO2 at ambient conditions by a conjugated microporous polymer
Conjugated microporous polymers are a new class of porous materials with an extended π-conjugation in an amorphous organic framework. Owing to the wide-ranging flexibility in the choice and design of components and the available control of pore parameters, these polymers can be tailored for use in various applications, such as gas storage, electronics and catalysis. Here we report a class of co...
متن کاملSynthesis of metalloporphyrin-based conjugated microporous polymer spheres directed by bipyridine-type ligands.
Zinc porphyrin (TP-Zn)-based conjugated microporous polymer (Zn-CMP) spheres were obtained via Sonagashira-Hagihara cross coupling reactions between 5,10,15,20-tetrakis(4-ethynylphenyl)porphyrin-Zn(II) and brominated monomers directed by bidentate bipyridine (BP)-type ligands for the first time, and the sphere diameters could be adjusted from 320 to 740 nm. The coordination between BP and TP-Zn...
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ژورنال
عنوان ژورنال: Protocol Exchange
سال: 2013
ISSN: 2043-0116
DOI: 10.1038/protex.2013.056